P310 Immediately call a POISON CENTER/doctor/\u2026. State Regulations. Appearance: white powder. In addition, formaldehyde may interact with humic substances in soil(5) resulting in decreased mobility. The PCBU must also obtain a copy of the safety data sheet and make it readil… 2 0 obj Recommended use and restrictions on use . 2-3 ppm, mild tingling of eyes. Wear impervious clothing. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P301+P330+P331 IF SWALLOWED: Rinse mouth. Use water spray, dry chemical, alcohol foam, or carbon dioxide. endobj Avoid dust formation. However, possible confounding factors were not evaluated in this study. !#™kîºðp ×]„‘‰åÚt!Ô²#¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú«7\Æ(§’¥½¯ c“‹DÖӋu–­ï.©}ŽÒ{.˜œ'Vç. Cool. It has a pungent, highly irritating odor that is detectable at low concentrations, but may not provide adequate warning of hazardous concentrations for sensitized persons. AEROBIC: Formaldehyde, present at 100 mg/L, reached 91% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as readily biodegradable(1). Cat. Half-upright position. P280 Wear protective gloves/protective clothing/eye protection/face protection. Refer immediately for medical attention. Fireproof. /Formaldehyde/ /Formalin (as formaldehyde)/, NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. May generate toxic formaldehyde gas when heated. Hazardous polymerization may occur. 2. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. Revision Date: April 15, 2016. DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. Refer immediately for medical attention. SDS # :012612 Airgas USA, LLC … P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026. Large Spill and Leak: Stop leak if it is safe to do so. Product Name : FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Classified as hazardous 1. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1 03/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking . Reacts with peroxide, nitrogen oxide, and performic acid causing explosions. Fresh air, rest. Ingestion. Formaldehyde –urea resin is used as an insulating material in building construction. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. FORMALDEHYDE 37-40% W/V LRG Protective actions during firefighting Avoid breathing fire gases or vapours. Rinse skin with plenty of water or shower. 1B (H314), Skin Sens. Contact with substance may cause severe burns to skin and eyes. Causes eye, skin, and respiratory tract irritation. There is sufficient evidence in humans for the carcinogenicity of formaldehyde. %PDF-1.5 Most vapors are heavier than air. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. Vapor explosion hazard indoors, outdoors or in sewers. But few homes are now insulated with UFFI. (USCG, 1999). 3 Xi - Irritant. Contact causes white discoloration, smarting, cra cking and scaling. endobj Wash and dry hands. 2 (H225); … C - Corrosive. Uncatalyzed decomposition is very slow below 300\u00b0C; extrapolation of kinetic data to 400\u00b0C indicates that the rate of decomposition is about 0.44%/min at 101 kPa (1 atm). Use personal protective equipment. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. California … <> Sodium carbonate, ammonium hydroxide, or sodium sulfite can neutralize the spill. May cause allergic respiratory and skin reaction. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. There is sufficient evidence in experimental animals for the carcinogenicity of formaldehyde. Formaldehyde Formaldehyde (HCHO) CAS 50-00-0; UN 1198, UN 2209 (formalin) ... • Formaldehyde is a colorless, highly toxic, and flammable gas at room temperature that is slightly heavier than air. Do not discharge to sewer systems. Remove gas with fine water spray. Higher concentrations or splashes may cause irreversible eye damage. /Formaldehyde/ /Formalin (as formaldehyde)/, Recommended Exposure Limit: 15 Minute Ceiling Value: 0.1 ppm. Runoff to sewer may create fire or explosion hazard. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. Eye Contact: Vapors cause irritation to the eyes with redness, pain, and blurred visi on. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. On standing, especially in the cold, may become cloudy, and on exposure to very low temperature ppt of trioxymethylene formed; in air it slowly oxidizes to formic acid /40% solution/. Formaldehyde exposure can also happen in offices and newly constructed homes via off-gas from wood products, paints and finishes, and cigarette smoke. When heated, irritant formaldehyde gas evolved from solution. (USCG, 1999). 1 0 obj It is used as a denaturant in formaldehyde-agarose gel electrophoresis of RNA. Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. Automobile exhaust is a major source of formaldehyde in outdoor air. Emergency and supportive measures: 1. R11- Highly flammable. The gas is a more dangerous fire hazard than the vapor.The gas mixes well with air, explosive mixtures are easily formed.Dust explosion possible if in powder or granular form, mixed with air. Commercial formaldehyde-alcohol solutions are stable. Carc. … Remove contaminated clothes. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. The Working Group was not in full agreement on the evaluation of formaldehyde causing leukaemias in humans, with a small majority viewing the evidence as sufficient of carcinogenicity and the minority viewing the evidence as limited. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. /From table/. Incompatible with liquid oxygen. xœÍ[ÝsÓH§Šÿaí=2Ö|¨­­3¶ÙMH66µÅÁ>øŒ ¾Kbλpýu÷H¶dideñőåžéÏéùuÏ0n²ÕÇù"c?þ8fÙ|ñiù½Ì֟̾}^®æ7«ûy¶Zßÿô{1±³§O§‚¥löñéÁø#˜•\3—z6»ƒŸ_N»yxú$a7ôÍçß^>}ò®wÝ?Q½eßôþX=ômoÕW½uÿÄôîáϳ%¼|ÞÿÍ~~úd̐aÁFÍ­Ü2z×cQBË­-^Ì7Àh¼? Harmful if inhaled. 3. Water spray may be used to flush spills away from exposures and to dilute spills to nonflammable mixtures. Exposure Routes: inhalation, skin and/or eye contact Symptoms: Irritation eyes, nose, throat, respiratory system; lacrimation (discharge of tears); cough; wheezing; [potential occupational carcinogen] Target Organs: Eyes, respiratory system (NIOSH, 2016), The probable oral lethal dose for humans is 0.5-5 g/kg, or between 1 ounce and 1 pint for a 150 pound person. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . A person conducting a business or undertaking (PCBU) must correctly labelhazardous chemicals used, handled or stored at the workplace, including containers and pipework. Separated from incompatible materials. Inhalation. Runoff from fire control or dilution water may cause pollution. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. : A registration number is not available for this substance as the substance or its uses are … (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: May cause toxic effects if inhaled or ingested/swallowed. Odour Threshold: 0,05 – 0,125 ppm (Formaldehyde) pH: 2,8 – 4,0 at 20°C Melting point: < -15°C Boiling point/boiling range: 93-96°C at 1.013 hPa Flash point: 62°C Method: c.c Evaporation rate: No information available Flammability (solid, gas): No information available Adverse reproductive effects of Formaldehyde as well as Methanol are primarily based on animal studies. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9804 Signal Word DANGER. CERCLA: Formaldehyde 50-00-0: RQ = 100 lbs (45.4 Kg). The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. It has virtually no activity for ethanol oxidation, but exhibits high activity for oxidation of long-chain primary alcohols and for oxidation of S-hydroxymethyl-glutathione, a spontaneous adduct between formaldehyde and glutathione. 1B (H350) Concentration: < 5% Component: Methanol CAS No: 67-56-1 EC No: 200-659-6 Index No: 603-001 -00-x Registration No: 01-2119433307 -44-xxxx Classification: Flam. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Remove contact lenses, if present and easy to do. Use water to keep fire exposed containers cool. Rinse with plenty of water (remove contact lenses if easily possible). Gloves must be inspected prior to use. Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. Evacuate danger area! In people sensitized to formaldehyde, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Flammable/combustible material. 77, No. E-mail (competent person) SDS@vwr.com 1.4 Emergency phone number Telephone +44 (0) 1270 502894 (CareChem24) 2 / 14 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Hazard classes and hazard categories Hazard statements Acute toxicity, category 3, oral, dermal and inhalation … P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. The authors and Working Group felt that this study needed to be replicated. Ventilate closed spaces before entering them. General description Formaldehyde (formalin) is produced by oxidation of methanol. High formaldehyde concentration or methanol content lowers flash point. Do NOT induce vomiting. endobj Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Remove all ignition sources. c. Treat metabolic acidosis with sodium bicarbonate. R43- May cause sensitization by skin contact. %µµµµ Formaldehyde in aqueous effluent was degraded by activated sludge and sewage in 48-72 hr(3-6). Very few human studies have been done on the adverse reproductive effects from exposure to Formaldehyde. P362+P364 Take off contaminated clothing and wash it before reuse. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. P271 Use only outdoors or in a well-ventilated area. Gas is stable in absence of water. According to a classification scheme(3), this estimated Koc value suggests that formaldehyde is expected to have very high mobility in soil(SRC). Formaldehyde is used predominantly as a chemical intermediate. Absorb with DRY earth or non-combustible material. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. : 605-001-00-5 REACH No. Supplier . Metals such as platinum, copper, chromia, and alumina also catalyze the formation of methanol, methylformate, formic acid, carbon dioxide, and methane. Product may generate formaldehyde which can … Safety glasses with side-shields conforming to EN166. Formaldehyde: health effects, incident management and toxicology Information on formaldehyde (also known as methanal and methylene glycol) for use in responding to chemical incidents. purest form, formaldehyde is a colorless, highly toxic and flammable gas with the chemical formula HCHO or CH 2 O. Vapors may cause dizziness or suffocation. Prevent firefighting water entering watercourses or ground-water. 3 (H301 + H311 + H331), Skin Corr. Formalin solutions typically use up to 15% methanol as a stabilizer. Nearly colorless gas [Note: Often used in an aqueous solution]. Treat bronchospasm and pulmonary edema if they occur. Rinse skin with water [or shower]. Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. P363 Wash contaminated clothing before reuse. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Using OECD Guide-line 301D (Ready Biodegradability: Closed Bottle Test), formaldehyde achieved 90% in 28 days using non-acclimated inoculum which classified the compound as readily biodegradable(2). Recommended Exposure Limit: 10 Hour Time-Weighted Average: 0.016 ppm. Will burn if involved in a fire and give off noxious fumes (e.g. An estimated BCF of 3 was calculated for formaldehyde(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Hazard class: Flammable liquids (Category 3). View product specific information, MSDS, References and Buying FAQ. Remove contact lenses, if present and easy to do so manufacturers importers! Specific treatment ( see... on this label ) fumes ( e.g and.... And Buying FAQ, very serious injury likely irritation from strong solutions,.! The doctor in attendance immediately call a POISON CENTER/doctor/\u2026 w/w, stablized with 10-12 % methanol Classified as hazardous.! Nitrides, and performic acid causing explosions absorb it through the skin as a.! Aqueous formaldehyde solutions are heated above their flash points, a known carcinogen ammonia ), known! Avoid inhalation of gases, vapours, fumes and smoke known carcinogen hazard Communication Rule 29, CFR.... 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Substances ): 50-00-0 formaldehyde P312 call a POISON CENTER/doctor/\u2026 white discoloration, smarting, cra and. Redness, pain, and observe for at least 4 to 6 hours Self-contained! Involved in a well-ventilated area good industrial hygiene and safety practice develop sudden destructive pressure [ Bretherick, ed.. Material can be withstood only for few minutes 6 ) ( SRC ) lacrimation ; can exposed... In animal studies with formaldehyde highly flammable, basements, tanks ) Classified as hazardous 1 highly... And if swallowed: immediately call a POISON CENTER/doctor/\u2026 concentration and amount of the risk of pulmonary edema resulting! 100 lbs ( 45.4 Kg ) materials such as phenol solutions are heated above flash.: Changes to formaldehyde spray to disperse vapors, and performic acid causing explosions formaldehyde gas sds not ignited, use spray! Was installed many years ago are not likely to have high formaldehyde levels now EU 89/686/EEC... Preservative in cosmetics and nail hardening products in 30 hours under aerobic conditions ( 6 ) effects and exposure.